The situation is as follows (I changed to more standard-ish Haskell notation):
class Functor f => MonoidallyCopointed f where
    copointAppend ::  (∀r.f(r)->r) -> (∀r.f(r)->r) -> (∀r.f(r)->r)
    copointEmpty  ::  ∀r.f(r)->r
such that for all instance F of MonoidallyCopointed and for all
x,y,z::∀r.F(r)->r
The following holds:
x `copointAppend` copointEmpty == copointEmpty `copointAppend` x == x
x `copointAppend` (y `copointAppend` z) == (x `copointAppend` y) `copointAppend` z
Then is it true that F has a natural Comonad instance defined from copointAppend and copointEmpty?
N.B. The converse holds (with copointEmpty = extract and copointAppend f g = f . g . duplicate.)
EDIT
As Bartosz pointed out in the comment, this is mostly the definition of comonads using the co-Kleisli adjunction. So the question is really about the constructivity of this notion. Accordingly, the following question is probably more interesting in terms of real-world applications:
Does there exist a constructive isomorphism between the set of possible Comonad instances of f and the set of possible MonoidallyCopointed instances of f?
This can be useful in practice because a direct definition of Comonad instance can involve a bit of
technical, hard-to-read code that cannot be verified by the type checker. For example,
data W a = W (Maybe a) (Int -> a) (Either (String -> a) (a,a,a,a))
has a Comonad instance but the direct definition (with the proof that it's indeed a Comonad!) may not be so easy.
On the other hand, providing a MonoidallyCopointed instance may be a little easier (but I'm not perfectly
sure of this point).